Tandem deuteration/hydrosilylation reactions catalyzed by a rhodium carbene complex under solvent-free conditions |
| |
Authors: | Egbert Jonathan D Nolan Steven P |
| |
Institution: | EaStCHEM School of Chemistry, University of St Andrews, St Andrews, KY16 9ST, UK. |
| |
Abstract: | The complex Rh(I(t)Bu)(2)HCl] has been shown to be an active catalyst in the hydrosilylation of carbonyl and imine complexes. This reactivity, combined with the previously reported H/D exchange catalyzed by these complexes allows for a one pot, two step reaction using a single catalyst for both H/D exchange and hydrosilylation. Using triethylsilane, Rh(I(t)Bu)(2)Cl] catalyst, and D(2) gas, deuterated silyl-ethers can be synthesized in an atom-economical, solvent-free reaction. |
| |
Keywords: | |
本文献已被 PubMed 等数据库收录! |
|