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Carborane photochemistry triggered by aryl substitution: carborane-based dyads with phenyl carbazoles
Authors:Wee Kyung-Ryang  Han Won-Sik  Cho Dae Won  Kwon Soonnam  Pac Chyongjin  Kang Sang Ook
Institution:Department of Materials Chemistry, Korea University, Chungnam, South Korea.
Abstract:A bright combination: a new type of donor-acceptor dyad, carbazolylaryl-substituted ortho-carboranes, which are conveniently prepared from the corresponding acetylenes and decaborane pathways, showed unique excited-state behavior associated with electron transfer unlike the meta- and para-counterparts.
Keywords:boranes  cage compounds  electron transfer  photophysics
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