Iterative asymmetric allylic substitutions: syn- and anti-1,2-diols through catalyst control |
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| Authors: | Park Jin Kyoon McQuade D Tyler |
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| Affiliation: | Department of Chemistry & Biochemistry, Florida State University, Tallahassee, 32306-4390, USA. |
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| Abstract: | A copper-catalyzed asymmetric allylic boronation (AAB) gives access to syn- and anti-1,2-diols. The method facilitates an iterative strategy for the preparation of polyols, such as the fully differentiated L-ribo-tetrol and protected D-arabino-tetrol. P=protecting group. |
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| Keywords: | allylic substitution boronation copper homogeneous catalysis iterative asymmetric reaction |
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