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| 非水系锂空气电池的正极材料和电解液研究进展 | |
| 引用本文： | 杨凤玉,张蕾蕾,徐吉静,刘清朝,赵敏寿,张新波. 非水系锂空气电池的正极材料和电解液研究进展[J]. 无机化学学报, 2013, 29(8): 1563-1573 |
| 作者姓名： | 杨凤玉 张蕾蕾 徐吉静 刘清朝 赵敏寿 张新波 |
| 作者单位： | 中国科学院长春应用化学研究所, 稀土资源利用国家重点实验室, 长春 130022;燕山大学, 环境与化学工程学院, 秦皇岛 066004;中国科学院长春应用化学研究所, 稀土资源利用国家重点实验室, 长春 130022;中国科学院大学, 北京 100049;中国科学院长春应用化学研究所, 稀土资源利用国家重点实验室, 长春 130022;中国科学院长春应用化学研究所, 稀土资源利用国家重点实验室, 长春 130022;吉林大学, 材料科学与工程学院, 长春 130012;燕山大学, 环境与化学工程学院, 秦皇岛 066004;中国科学院长春应用化学研究所, 稀土资源利用国家重点实验室, 长春 130022 |
| 基金项目： | 中国科学院“百人计划”;国家重点基础研究发展计划(No.2012CB215500);国家自然科学基金(No.20921002,21101147,21203176)资助项目。 |
| 摘 要： | 锂空气电池的能量密度是传统锂离子电池的5~10倍,可与汽油相媲美。近几年来,锂空气电池因此受到了人们的广泛关注。本文概述了锂空气电池正极材料和电解液的最新研究进展。从商业碳、具有特定形态的碳材料、催化剂、导电聚合物等几个方面阐述了正极材料;从物质结构的角度,简要介绍了锂空气电池中常用的酯类、醚类、砜类、胺类和离子液体等电解液。最后指出了目前锂空气电池存在的问题,并对其进行了展望。 |
| 关 键 词： | 锂空气电池 正极材料 催化剂 电解液 |
| 收稿时间： | 2013-04-03 |
| 修稿时间： | 2013-05-17 |
Progress of Cathode Material and Electrolyte in Non-aqueous Li-Air Battery |
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| YANG Feng-Yu,ZHANG Lei-Lei,XU Ji-Jing,LIU Qing-Chao,ZHAO Min-Shou and ZHANG Xin-Bo. Progress of Cathode Material and Electrolyte in Non-aqueous Li-Air Battery[J]. Chinese Journal of Inorganic Chemistry, 2013, 29(8): 1563-1573 | |
| Authors: | YANG Feng-Yu ZHANG Lei-Lei XU Ji-Jing LIU Qing-Chao ZHAO Min-Shou ZHANG Xin-Bo |
| Affiliation: | State Key Laboratory of Rare Earth Resource Utilization, Changchun Institute of Applied Chemistry, Chinese Academy of Sciences, Changchun 130022, China;School of Environment and Chemical Engineering, Yanshan University, Qinhuangdao, Hebei 066004, China;State Key Laboratory of Rare Earth Resource Utilization, Changchun Institute of Applied Chemistry, Chinese Academy of Sciences, Changchun 130022, China;University of Chinese Academy of Sciences, Beijing 100049, China;State Key Laboratory of Rare Earth Resource Utilization, Changchun Institute of Applied Chemistry, Chinese Academy of Sciences, Changchun 130022, China;State Key Laboratory of Rare Earth Resource Utilization, Changchun Institute of Applied Chemistry, Chinese Academy of Sciences, Changchun 130022, China;School of Materials Science and Engineering,Jilin University, Changchun 130012, China;School of Environment and Chemical Engineering, Yanshan University, Qinhuangdao, Hebei 066004, China;State Key Laboratory of Rare Earth Resource Utilization, Changchun Institute of Applied Chemistry, Chinese Academy of Sciences, Changchun 130022, China |
| Abstract: | A Li-air battery could provide much higher energy density than conventional lithium-ion battery, which is comparable to gasoline and, thus, many attentions have been paid to the Li-air battery in recent years. This paper summarizes the latest development of the cathode material and electrolyte in the non-aqueous Li-air battery. The cathode materials concern commercial carbon, artificial carbon with a defined morphology, catalyst and conducting polymer. Electrolytes concern widely used solvents including ester, ether, sulfone, amine and ionic liquid. Finally, the main problems in the non-aqueous Li-air battery have been pointed out and look forward to the future on non-aqueous Li-air battery. |
| Keywords: | Li-air battery cathode material catalyst electrolyte |
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