Binuclear metal-catecholato complexes |
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| Authors: | Mauro Ghedini Giovanni De Munno Gianfranco Denti Giuliano Dolcetti |
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| Institution: | (1) Department of Chemistry, Università della Calabria, 87030 Arcavacata (CS), Italy;(2) Present address: Istituto di Chimica, Università di Udine, Viale Ungheria 43, 33100 Udine, Italy |
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| Abstract: | Summary The synthesis and characterisation of the products obtained by reaction of 3,4-dihydroxybenzaldehydeazine, H4DBA, and iridium nitrosyl or platinum, palladium and nickel phosphine complexes are reported. The relation between the complexes, stability and the electron withdrawing power of the ligands is considered. With nickel, for which only the parent mononuclear complexes, L2Ni(catechol), were obtained, the influence of the neutral ligand L is discussed. |
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