The infrared spectrum of C2F5Cl in cryogenic matrices |
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Authors: | S.Nunziante Cesaro M. Maltese C.D. Cantrell |
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Affiliation: | Istituto di Chimica Fisica, Università di Roma, 00185 Rome, Italy;Istituto di Chimica Generale ed Inorganica, Università di Roma, 00185 Rome, Italy;Center for Quantum Electronics and Applications, University of Texas at Dallas, P.O. Box 688, Richardson, Texas 75080 USA |
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Abstract: | We have measured the infrared spectrum of pentafluoroethyl chloride in cryogenic matrices of argon, nitrogen, krypton, and xenon from 880 to 1360 cm?1. Numerous combination bands were observed; assignments and symmetries are reported for most. Appreciably more structure was observed in argon than in other matrices. The observed splitting of the fundamental bands in an argon matrix into two or more components may be due to multiple trapping sites. |
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