Synthesis, characterization, and near-infrared luminescent properties of the ternary thulium complex covalently bonded to mesoporous MCM-41 |
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Authors: | Jing Feng Shu-Yan Song Yan Xing Zhe-Feng Li Li-Ning Sun Wei-Qiang Fan |
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Affiliation: | a State Key Laboratory of Rare Earth Resource Utilizations, Changchun Institute of Applied Chemistry, Chinese Academy of Sciences, Changchun 130022, PR China b Graduate School of the Chinese Academy of Sciences, Beijing, PR China |
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Abstract: | The crystal structure of a ternary Tm(DBM)3phen complex (DBM=dibenzoylmethane; phen=1, 10-phenanthroline) and the synthesis of hybrid mesoporous material in which the complex covalently bonded to mesoporous MCM-41 are reported. Crystal data: Tm(DBM)3phen C59H47N2O7Tm, monoclinic, P21/c, a=19.3216(12) Å, b=10.6691(7) Å, c=23.0165(15) Å, α=90°, β=91.6330(10)°, γ=90°, V=4742.8(5) Å3, Z=4. The properties of the Tm(DBM)3phen complex and the corresponding hybrid mesoporous material [Tm(DBM)3phen-MCM-41] have been studied. The results reveal that the Tm(DBM)3phen complex is successfully covalently bonded to MCM-41. Both Tm(DBM)3phen complex and Tm(DBM)3phen-MCM-41 display typical near-infrared (NIR) luminescence upon excitation at the maximum absorption of the ligands, which contributes to the efficient energy transfer from the ligands to the Tm3+ ion, an antenna effect. The full width at half maximum (FWHM) centered at 1474 nm in the emission spectrum of Tm(DBM)3phen-MCM-41 is 110 nm, which is the potential candidate of broadening amplification band from C band (1530-1560 nm) to S+ band (1450-1480 nm) in optical area. |
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Keywords: | MCM-41 Thulium complex Covalently bonded Near-infrared luminescence Optical telecommunication |
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