A Novel Supramolecular Complex Based on Zaltoprofen Ligand: Synthesis,Crystal Structure,and Properties |
| |
| Authors: | Xia Yin Jin-Niu Tang Gang-Hong Pan Wei-Man Tian Wen-Jia Xu Zhong-Jing Huang |
| |
| Affiliation: | 1. The NO. 2 Middle School of Dongkou Hunan, Dongkou, P.R. China;2. College of Chemistry and Chemical Engineering, Guangxi University for Nationalities, Nanning, P.R. China |
| |
| Abstract: | A novel metal-organic supramolecular complex [Zn2 (Zaltoprofen)2(phen)2] (where Zaltoprofen = 5-(1-carboxyethyl)-2-(phenylthio)phenylacetic acid, phen = 1,10-phenanthroline) has been synthesized under hydrothermal condition and characterized by single crystal X-ray diffraction, elemental analysis, spectral method (IR), powder X-ray diffraction (XRD), electronic Spectra (UV-vis), and fluorescent properties. The compound crystallizes in the monoclinic P2(1)/c space group. [Zn2(Zaltoprofen)2(phen)2] features 0-D structural, the π–π stacking interactions and C?H···O hydrogen-bonds play a vital role in determining the crystal packing and construction of the extended 3-D supramolecular network. |
| |
| Keywords: | Crystal structure photoluminescence properties zaltoprofen π–π stacking |
|
|
