| Unprecedented α-Octamolybdate Derivative Containing Hexad-track Cu―bpe Chains,2{[Cu(bpe)]_6[α-Mo_8O_(26)]_(3/2)}·[Cu(bpe)]_3·3H_2O |
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| 基金项目： | Supported by the National Natural Science Foundation of China(Nos.20901031 and 21071029); the Natural Science Foundation of Heilongjiang Province,China(No.B200916); the Education Ministry Key Teachers Foundation of Heilongjiang Province,China(No.1155G53); the Talent Training Fund of Jiamusi University, China(No.RC2009-034) |
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| 摘 要： | A new inorganic-organic hybrid constructed from α-octamolybdate polyoxometalates modified by hexad- track Cu―bpe chains, 2{[Cu(bpe)]6[α-Mo8O26]3/2}·[Cu(bpe)]3·3H2O[1, bpe=bis(4-pyridyl)ethylene], has been synthesized and structurally characterized. X-Ray diffraction analysis reveals that each α-octamolybdate cluster links six transition metal complex chains and the title compound has represented the highest connective number of M―N chains modified octamolybdate POMs to date. Note that there are two crystall...
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