| 叶绿素衍生物的合成及其对紫细菌原初光化学特性 的影响研究 |
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| 引用本文： | 陈志龙,陈静蓉,邹永龙,吴毓林,曾小华,徐春和. 叶绿素衍生物的合成及其对紫细菌原初光化学特性 的影响研究[J]. 化学学报, 2001, 59(8): 1310-1316 |
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| 作者姓名： | 陈志龙 陈静蓉 邹永龙 吴毓林 曾小华 徐春和 |
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| 作者单位： | 第二军医大学海军医学系.上海(200433);中国科学院上海生命科学研究院;植 物生理生态研究所;中国科学院上海有机化学研究所.上海(200032) |
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| 基金项目： | 国家自然科学基金(29872055,30070862)和国家973重点基金(G1998010100)资助项目 |
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| 摘 要： | 对10个叶绿素衍生物的合成方法进行了研究，在一定的温度(43.5℃)和丙酮的协同作用下，植物脱镁叶绿素a可转换紫细菌RS601光合反应中心的细菌脱镁叶绿素，光化学活性为对照的71.4%，光化学活性的下降与替代色素的变化无对应关系，替代后降低了Bphe^-/Bphe和QA^-/QA电对之间的电子传递速率。
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| 关 键 词： | 叶绿素 原初过程 紫细菌 光化学 光合作用 合成法 |
| 修稿时间： | 2000-10-08 |
The synthsis of chlorophyll derivatives and their photosynthetic activit in purple bacteria reaction centers |
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| Chen Zhilong,Chen Jingrong,Zou Yonglong,Wu Yulin,Zeng Xiaohua,Xu Chunhe. The synthsis of chlorophyll derivatives and their photosynthetic activit in purple bacteria reaction centers[J]. Acta Chimica Sinica, 2001, 59(8): 1310-1316 |
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| Authors: | Chen Zhilong Chen Jingrong Zou Yonglong Wu Yulin Zeng Xiaohua Xu Chunhe |
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| Affiliation: | Faculty of Naval Medical, Second Military Medical University.Shanghai (200433);Shanghai Inst Organ Chem., CAS.Shanghai(200032) |
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| Abstract: | Ten chlorophyll derivatives were synthesized and five of them were reported for the first time. In the presence of acetone and an excess of exogenous plant pheophytins, bacteriopheophytins in the reaction centers from Phodobacter sphaeroides RS601 were replaced by the pheophytins at sites HA and HB. When incubated at 43.5℃ for 60min, the photochemical activities of the pheophytin reaction centers are 71.4% of the control. The electron transfer rate of Bphe^-/Bphe(phe^- /phe) and QA^-/QA was decreased. |
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| Keywords: | CHLOROPHYLL PHOTOCHEMISTRY PHOTOSYNTHESIS SYNTHESIS METHODS |
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