Response surface methodology for the optimization of the ultrasonic-assisted rhamnolipid treatment of oily sludge |
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Authors: | Chong Liu Xuefei Hu Qi Xu Simin Zhang Pengyan Zhang Huanliang Guo Yongjun You Zhengjie Liu |
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Affiliation: | 1. State Key Laboratory of Heavy Oil Processing, Beijing Key Laboratory of Oil & Gas Pollution Control, Institute of Chemical Engineering and Environment, China University of Petroleum-Beijing, Beijing 102249, PR China;2. Institute of Water Resource and Architectural Engineering, Tarim University, Alar, Xinjiang 843300, PR China;3. Shenzhen Shenshui Ecological & Environmental Technology Co., Ltd., Shenzhen 518000, PR China |
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Abstract: | This study investigates the recovery of oily sludge using ultrasound-assisted rhamnolipids and uses oil recovery yield as an evaluation index. The Box–Behnken response surface method was employed to investigate the individual and interactive effects of four different operating factors: frequency, dosage, liquid–solid ratio, and stirring speed. The model optimization results showed that the order of degree of influence of these four factors is frequency > liquid–solid ratio > dosage > stirring speed. The mathematical model predicted the highest oil recovery yield as 92.27%, which was highly accurate (in the 95% confidence interval) as from the experimental results, the highest oil recovery yield was 89.95% under optimal reaction conditions (frequency = 25.58 kHz, dosage = 150.45 mg/L, liquid–solid ratio = 4.1:1 mL/g, and stirring speed = 407 rpm). Thus, the deviation from the prediction model was only 2.32%, indicating that this method provides a theoretical basis for the treatment of oily sludge and can be implemented for practical application in Huaidong in the Xinjiang Province. |
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Keywords: | Rhamnolipid Ultrasound Response surface Oily sludge Biosurfactant CMC" },{" #name" :" keyword" ," $" :{" id" :" k0035" }," $$" :[{" #name" :" text" ," _" :" critical micelle concentration CV" },{" #name" :" keyword" ," $" :{" id" :" k0045" }," $$" :[{" #name" :" text" ," _" :" coefficient of variance IFT" },{" #name" :" keyword" ," $" :{" id" :" k0055" }," $$" :[{" #name" :" text" ," _" :" interfacial tension PHC" },{" #name" :" keyword" ," $" :{" id" :" k0065" }," $$" :[{" #name" :" text" ," _" :" petroleum hydrocarbon RH" },{" #name" :" keyword" ," $" :{" id" :" k0075" }," $$" :[{" #name" :" text" ," _" :" rhamnolipid SARA" },{" #name" :" keyword" ," $" :{" id" :" k0085" }," $$" :[{" #name" :" text" ," _" :" saturates, aromatics, resins, and asphaltene US" },{" #name" :" keyword" ," $" :{" id" :" k0095" }," $$" :[{" #name" :" text" ," _" :" ultrasonic C.I." },{" #name" :" keyword" ," $" :{" id" :" k0105" }," $$" :[{" #name" :" text" ," _" :" confidence interval |
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