Metric engineering of perfluorocarbon-hydrocarbon layered solids driven by the halogen bonding |
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| Authors: | Metrangolo Pierangelo Pilati Tullio Resnati Giuseppe Stevenazzi Andrea |
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| Affiliation: | Department of Chemistry, Materials, and Chemical Engineering G. Natta, Polytechnic of Milan, Via L. Mancinelli 7, 20131 Milan, Italy. pierangelo.metrangolo@polimi.it |
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| Abstract: | The halogen bonding driven self-assembly of 1,4-dicyanobutane and 1,6-dicyanohexane with a range of perfluorinated telechelic diiodoalkanes yields layered 1D, infinite chain co-crystals. The structure and metrics of these co-crystals are remarkably predictable. |
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