A Dumbbell Shaped Fullerene Dimer with An Inorganic Linker. Addition of C60 and Tetracyanoethylene to Ir2(CO)2Cl2(Ph2P(CH2)nPPh2)2 (n=5 or 7) |
| |
| Authors: | Joong W Lee Marilyn M Olmstead Jess S Vickery Alan L Balch |
| |
| Institution: | (1) Department of Chemistry, University of California, Davis, California, 95616 |
| |
| Abstract: | The centrosymmetric dimers, (
2-C60)2Ir2(CO)2Cl2( -Ph2P(CH2)7PPh2)2 and (
2-TCNE)2Ir2(CO)2Cl2(-Ph2P(CH2)5PPh2)2, have been prepared by the reactions of C60 with Ir2(CO)2Cl2(-Ph2P(CH2)7PPh2)2 and of tetracyanoethylene (TCNE) with Ir2(CO)2Cl2(-Ph2P(CH2)5PPh2)2, respectively. The structures of both adducts have been elucidated by single crystal X-ray diffraction studies. |
| |
| Keywords: | fullerene dimer iridium tetracyanoethylene |
| 本文献已被 SpringerLink 等数据库收录！ |
