Novel catalyst for dihydrogen evolution from water based on rhodium complexes with polyethyleneimine |
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| Authors: | E. R. Buyanova L. G. Matvienko A. I. Kokorin G. L. Elizarova V. N. Parmon K. I. Zamaraev |
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| Affiliation: | (1) Institute of Catalysis, Novosibirsk, USSR;(2) Institute of Chemical Physics, Moscow, USSR |
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| Abstract: | Catalytic activity of homogeneous and heterogeneous rhodium complexes with polyethyleneimine or ethylenediamine at various Rh:N ratios has been studied in the reaction of water reduction to dihydrogen by Vaq2+ and Craq2+ and the applicability of these catalysts for photocatalytic evolution of H2 from water is discussed.
                        Rh:N   Vap2+ Craq2+     .
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