Novel catalyst for dihydrogen evolution from water based on rhodium complexes with polyethyleneimine |
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Authors: | E R Buyanova L G Matvienko A I Kokorin G L Elizarova V N Parmon and K I Zamaraev |
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Institution: | (1) Institute of Catalysis, Novosibirsk, USSR;(2) Institute of Chemical Physics, Moscow, USSR |
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Abstract: | Catalytic activity of homogeneous and heterogeneous rhodium complexes with polyethyleneimine or ethylenediamine at various Rh:N ratios has been studied in the reaction of water reduction to dihydrogen by V
aq
2+
and Cr
aq
2+
and the applicability of these catalysts for photocatalytic evolution of H2 from water is discussed.
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![iecy](/content/m245827028376tp8/xxlarge1077.gif) V
ap
2+
Cr
aq
2+
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