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Novel one-pot vicinal double C-acylation of styrenes and methacrylates by electroreduction
Authors:Yamamoto Yoshimasa  Maekawa Hirofumi  Goda Satoshi  Nishiguchi Ikuzo
Affiliation:Department of Chemistry, Nagaoka University of Technology, 1603-1, Kamitomioka-cho, Nagaoka, Niigata 940-2188, Japan.
Abstract:[reaction: see text] Electroreduction of styrenes or alkyl methacrylates in the presence of aliphatic acid anhydrides or N-acylimidazoles with an undivided cell equipped with zinc electrodes as the anode and the cathode brought about novel one-pot vicinal double C-acylation to afford the corresponding 1,4-diketones in satisfactory yields.
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