Novel one-pot vicinal double C-acylation of styrenes and methacrylates by electroreduction |
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Authors: | Yamamoto Yoshimasa Maekawa Hirofumi Goda Satoshi Nishiguchi Ikuzo |
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Affiliation: | Department of Chemistry, Nagaoka University of Technology, 1603-1, Kamitomioka-cho, Nagaoka, Niigata 940-2188, Japan. |
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Abstract: | [reaction: see text] Electroreduction of styrenes or alkyl methacrylates in the presence of aliphatic acid anhydrides or N-acylimidazoles with an undivided cell equipped with zinc electrodes as the anode and the cathode brought about novel one-pot vicinal double C-acylation to afford the corresponding 1,4-diketones in satisfactory yields. |
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