Synthesis and structure of [Zn(OMe)(L)] x [Zn(OH)(L)] x 2(BPh4), L = cis,cis-1,3,5-tris[(E,E)-3-(2-furyl)acrylideneamino]cyclohexane: structural models of carbonic anhydrase and liver alcohol dehydrogenase |
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| Authors: | Cronin Leroy Walton Paul H |
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| Institution: | Department of Chemistry, The University of York, Heslington, York, UK YO10 5DD. |
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| Abstract: | Direct reaction of Zn(OH)(L)]+, L = cis,cis-1,3,5-tris(E,E)-3-(2-furyl)acrylideneamino]cyclohexane, with methanol gives a mixture of the starting material and Zn(OMe)(L)]+; structural analysis of the complexes shows that they are models of reactive intermediates in the catalytic cycles of the zinc enzymes carbonic anhydrase and liver alcohol dehydrogenase. |
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