Microporous sensor: gas sorption, guest exchange and guest-dependant luminescence of metal-organic framework |
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| Authors: | Sapchenko Sergey A Samsonenko Denis G Dybtsev Danil N Melgunov Maxim S Fedin Vladimir P |
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| Affiliation: | Nikolaev Institute of Inorganic Chemistry, Siberian Branch of the Russian Academy of Sciences, Novosibirsk, Russian Federation. |
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| Abstract: | Zn(II)-containing metal-organic framework (MOF) [Zn(4)(dmf)(ur)(2)(ndc)(4)] (ndc(2-) = 2,6-naphtalenedicarboxylate, ur = urotropin, dmf = N,N'-dimethylformamide) was synthesized and characterized by X-ray crystallography and gas sorption analysis. Host MOF retains its crystallinity after guest removal and exchange. Single-crystal to single-crystal formation of different host-guest systems with benzene and ferrocene was investigated. Interesting guest-depended luminescence properties of the porous host framework were observed. |
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