A theory of the dielectric loss in the aligned nematic mesophase |
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Authors: | Mauro Ferrario Myron Evans |
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Institution: | Edward Davies Chemical Laboratories, University College of Wales, Aberystwyth, SY23 1NE, UK |
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Abstract: | A theory of dielectric absorption and dispersion in the nematic phase is developed which does not rely on the use of a nematic “director”. The major features of the spectrum are reproduced by using the fact that the autocorrelation functions 〈μ(0) · υ(t)〉 and 〈υ(t) · μ(0)〉 are no longer symmetry disallowed when the overall sample is anisotropic, as in the aligned nematic. Here μ is the dipole vector of the diffusing molecule and υ the centre of mass linear velocity. |
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