"Achiral" benzophenone ligand for highly enantioselective Ru catalysts in ketone hydrogenation |
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| Authors: | Mikami Koichi Wakabayashi Kazuki Aikawa Kohsuke |
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| Affiliation: | Department of Applied Chemistry, Tokyo Institute of Technology, Tokyo 152-8552, Japan. kmikami@o.cc.titech.ac.jp |
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| Abstract: | [reaction: see text] The chirality of an "achiral" benzophenone-based complex can be controlled. The benzophenone-based complex thus controlled affords high enantioselectivity in the catalytic asymmetric ketone hydrogenation (up to 99% ee, >99% yield). |
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