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Mechanical,thermal, and morphological properties of powder coating waste reinforced acetal copolymer
Institution:1. Polymers and Advanced Materials Research Group (PIMA), Universitat Jaume I, Av. Vicente Sos Baynat s/n, 12071 Castellón, Spain;2. Department of Materials Science and Engineering and Chemical Engineering, Universidad Carlos III, Av. Universidad 30, 28911 Leganés, Madrid, Spain
Abstract:The present study investigates the individual effects of three different thermosetting waste materials, used as fillers, on the mechanical, thermal and flow properties of acetal copolymers (POM). Different amounts ranging from 5% to 30% by weight of hydrolyzed powder coating recyclates were mixed as filler material in POM. The matrix and the fillers were first dry-mixed and then compounds were prepared through melt extrusion. The resulting compounds were cooled, granulated, and then standard tensile test bars were produced through use of an injection-molding machine. We investigated the mechanical and thermal properties of test specimens, and tensile strength, bending strength and impact strength were evaluated as a function of type and amount of filler material in the POM matrix. In addition, the change in melt flow index of POM/filler mixtures was determined, before and after extrusion. Furthermore, the morphology of the specimens was examined via electron microscopy. The results of this investigation are encouraging and present an innovative approach to reutilize hydrolyzed electrostatic powder coating wastes with thermoset structures as fillers in acetal copolymers.
Keywords:Powder coating  Recycling  Acetal copolymer  Extruder  Injection molding  Mechanical properties
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