| 双酚A和邻苯二甲酰氯芳香酯环状四聚体的分离及其晶体结构研究 |
| |
| 引用本文： | 姜洪焱,刘天西,陈天禄,莫志深,徐纪平.双酚A和邻苯二甲酰氯芳香酯环状四聚体的分离及其晶体结构研究[J].高等学校化学学报,1996,17(8):1310. |
| |
| 作者姓名： | 姜洪焱 刘天西 陈天禄 莫志深 徐纪平 |
| |
| 作者单位： | 中国科学院长春应用化学研究所, 长春 130022 |
| |
| 基金项目： | 福特中国研究与发展基金 |
| |
| 摘 要： | 双酚A和邻苯二甲酰氯芳香酯环状低聚物经硝基笨重结晶得到环状四聚体,利用GPC、MS(FAB)、1HNMR、IR、DSC和元素分析对其结构进行了表征。其晶体结构由广角X射线衍射法确定为正交晶系,晶胞参数为α=0.9676nm,b=0.8699nm,c=2.0859nm.每个晶胞中含有2个环状四聚体分子,晶体密度为1.36g·cm-3,对环状四聚体晶体衍射峰进行了详细的指标化。
|
| 关 键 词： | 环状四聚体 广角X射线衍射 晶胞参数 |
| 收稿时间： | 1995-07-31 |
Isolation and X-ray Crystallographic Stucture of Cyclic Tetramer Based on Bisphenol A and o-Phthaloyl Dichloride |
| |
| JIANG Hong-Yan,LIU Tian-Xi,CHEN Tian-Lu,MO Zhi-Shen,XU Ji-ping.Isolation and X-ray Crystallographic Stucture of Cyclic Tetramer Based on Bisphenol A and o-Phthaloyl Dichloride[J].Chemical Research In Chinese Universities,1996,17(8):1310. |
| |
| Authors: | JIANG Hong-Yan LIU Tian-Xi CHEN Tian-Lu MO Zhi-Shen XU Ji-ping |
| |
| Institution: | Changchun Institute of Applied Chemistry, Academia Sinica, Changchun 130022 |
| |
| Abstract: | The polycrystalline powder of the cyclic tetramer based on bisphenol Aand o-phthaloyldichloride has been prepared by recrystallization from nitrobenzene and its crystalstructure has been determined by Wide-Angle X-ray Diffraction( WAXD ).The unit cell is orthorhombic and its dimensions α=0.967 b=0.8699 nm,c=2.0859 nm.Space group belongs to Pmmm,With two tetramers per unit cell, the crystal density is 1.36 g·cm-3.Indices of crystal diffraction peaks are also detailed in the present work. |
| |
| Keywords: | Cyclic tetramer WAXD Unit cell parameter |
| 本文献已被 CNKI 等数据库收录！ |
| 点击此处可从《高等学校化学学报》浏览原始摘要信息 |
| 点击此处可从《高等学校化学学报》下载免费的PDF全文 |
|
