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Selective oxidation of terminal aryl and aliphatic alkenes to aldehydes catalyzed by iron(III) porphyrins with triflate as a counter anion
Authors:Chen Guo-Qiang  Xu Zhen-Jiang  Zhou Cong-Ying  Che Chi-Ming
Institution:Shanghai-Hong Kong Joint Laboratory in Chemical Synthesis, Shanghai Institute of Organic Chemistry, 354 Feng Lin Road, Shanghai, China.
Abstract:Fe(Por)CF(3)SO(3)] (Por = porphyrin dianion) can efficiently catalyze selective oxidation of terminal aryl alkenes and aliphatic alkenes to aldehydes in good to high yields under mild conditions.
Keywords:
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