Use of the hyper-crosslinked polystyrene sorbents “Styrosorb” for solid phase extraction of phenols from water |
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Authors: | M P Tsyurupa M M Ilyin A I Andreeva V A Davankov |
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Institution: | 1. Nesmeyanov-Institute of Organo-Element Compounds, Russian Academy of Sciences, 117813, Moscow, Russia
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Abstract: | The analytical HPLC procedure for the quantitation of trace amounts of phenol and chlorophenols in aqueous media has been supplemented with the on-line preconcentration of phenols in a sorption cartridge packed with microporous hyper-crosslinked polystyrene. The cartridge is coupled in succession with a reversed-phase analytical column, which is operated isocratically in an aqueous acetonitrile eluent (1:1, v/v). Phenol concentrations down to 0.5 μg/l can be detected using a simple 254 nm UV detector. Biporous hyper-crosslinked polystyrene-type sorbents were shown to effectively purify about 100 bed volumes of water from phenol under neutral or acidic conditions and linear flow rates up to 4 cm/min, which could be of great practical importance. Rapid and quantitative elution of sorbates from the hyper-crosslinked polystyrene materials is facilitated by the unique ability of the latter to additionally swell with organic or aqueous-organic eluents applied. |
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