Direct mono-insertion of isocyanides into terminal alkynes catalyzed by rare-earth silylamides |
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| Authors: | Komeyama Kimihiro Sasayama Daisuke Kawabata Tomonori Takehira Katsuomi Takaki Ken |
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| Institution: | Department of Chemistry and Chemical Engineering, Graduate School of Engineering, Hiroshima University, Higashi-Hiroshima 739-8527, Japan. kkome@hiroshima-u.ac.jp |
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| Abstract: | Rare-earth silylamide complexes, LnN(SiMe3)2]3 (Ln = Y, La, Sm, Yb), effectively catalyzed the coupling reaction of isocyanides with both aliphatic and aromatic terminal alkynes under mild conditions. |
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