Cobalt-pyridine bond strength in RCo[N,N′-ethylenebis(salicyclideneaminato)] (pyridine) R=Me,Et,n-Pr,i-Pr,n-Bu,i-Bu |
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| Authors: | C. T. Mortimer Jan M. B. Steele |
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| Affiliation: | (1) Chemistry Department, University of Keele, ST5 5BG Keele, Staffordshire, UK |
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| Abstract: | The use of differential scanning calorimetry has provided enthalpies, H (298 K), of the dissociation reactions RCo(salen) (pyridine) (c)  RCo(salen) (c)+pyridine(g)R=Me 34.5, Et 21.9,n-Pr 12.8,i-Pr 11.1,n-Bu 8.3 andi-Bu 13.5 kJ mol–1
Zusammenfassung Mit Hilfe der Differential-Scanning-Kalorimetrie wurden die EnthalpienH(298 K) der Dissoziationsreaktionen RCo(salen)(Pyridin)(c) RCo(saleo)(c)+Pyridin(g) bestimmt: R=Me 34,5, Et 21,9,n-Pr 12,8,i-Pr 11,1,n-Bu 8,3 undi-Bu 13,5 kJ·mol–1.
                            (298 K)  : R () () R ()+( )    R  R = – 34,5; – 21,9; - –12,8; - 11,1; - –8,3 13,5 · –1.
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