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Synthesis of tetrasubstituted and functionalized enol ethers by E-selective olefination of esters with ynolates
Authors:Shindo Mitsuru  Kita Taisuke  Kumagai Toshihiro  Matsumoto Kenji  Shishido Kozo
Institution:Institute of Health Biosciences, The University of Tokushima Graduate School, Japan. shindo@cm.kyushu-u.ac.jp
Abstract:We have developed the E-selective olefination of ester carbonyls to afford tetrasubstituted, functionalized olefins and the C-S insertion of thiol esters to give beta-keto thiol esters via ynolates.
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