The influence of the chemical nature of the cation in Y zeolites on the alkylation reaction of benzene with ethylene |
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| Authors: | Kh M Minachev E S Mortikov A A Masloboev N F Kononov N V Mirzabekova |
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| Institution: | 1. N. D. Zelinskii Institute of Organic Chemistry, Academy of Sciences of the USSR, Moscow
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| Abstract: | | 1. |
Given the same conditions on interaction between benzene and ethylene on the zeolites with Ca and REE, essentially ethylbenzene is formed; on the zeolites with the Ni and Fe cations essentially a secondary butylbenzene is formed; and on the zeolites with the trivalent Cr, a high-molecular-weight polyethylene is formed.
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A determining role of adsorption of one of the reactants in the change of the selectivity of zeolites with different cations has been demonstrated.
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