Synthesis and characterizations of N,N-bis(diphenylphosphino)ethylaniline derivatives and X-ray crystal structure of palladium (II), platinum (II) complexes |
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| Authors: | Feyyaz Durap Nermin Biricik Bahattin Gümgüm Saim Özkar Wee Han Ang Zhaofu Fei Rosario Scopelliti |
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| Institution: | 1. Department of Chemistry, University of Dicle, 21280 Diyarbakir, Turkey;2. Department of Chemistry, METU, 06531 Ankara, Turkey;3. Institut de Sciences et Ingénierie Chimiques, Ecole Polytechnique Fédérale de Lausanne, CH-1015 Lausanne, Switzerland |
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| Abstract: | N,N-Bis(diphenylphosphino)ethylaniline compounds, Ph2P]2N-C6H4-C2H5, with ethyl groups at the ortho- and para-positions have been synthesized. Oxidation of the aminophosphines with hydrogen peroxide, elemental sulfur and selenium gave the corresponding oxides, sulfides and selenides Ph2P(E)]2N-C6H4-C2H5 (E = O, S, Se). Complexes MCl2{(Ph2P)2N-C6H4-(C2H5)}] (M = Pd, Pt) and Cu{(Ph2P)2N-C6H4-C2H5}2]PF6 were obtained by the reaction of N,N-bis(diphenylphosphino)ethylaniline with MCl2(COD)] (M = Pd, Pt) and Cu(MeCN)4]PF6. The new compounds were characterized by NMR, IR spectroscopy and microanalysis. In addition, representative solid-state structures of the palladium and platinum complexes were determined using single crystal X-ray diffraction analyses. |
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| Keywords: | Aminophosphine Synthesis Oxidation Complexation X-ray structures |
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