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Simple protocol for the synthesis of the asymmetric PCP pincer ligand [C6H4-1-(CH2PPh2)-3-(CH(CH3)PPh2)] and its Pd(II) derivative [PdCl{C6H3-2-(CH2PPh2)-6-(CH(CH3)PPh2)}] |
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| Authors: | Ali Naghipour Zahra Haji Ghasemi David Morales-Morales Juan M. Serrano-Becerra Craig M. Jensen |
| Affiliation: | 1. Department of Chemistry, Faculty of Science, University of Ilam, Ilam 69315, Iran;2. Department of Chemistry, Azad University of Ilam, Ilam, Iran;3. Instituto de Química, Universidad Nacional Autónoma de México, Cd. Universitaria, Circuito Exterior, Coyoacán, 04510 México DF, Mexico;4. Department of Chemistry, University of Hawaii, Honolulu, HI 96822, USA |
| Abstract: | The asymmetric PCP pincer ligand [C6H4-1-(CH2PPh2)-3-(CH(CH3)PPh2)] (4) has been synthesized in a facile manner in three simple steps in high yield. Metallation of PCP pincer ligand (4) with [Pd(COD)Cl2] affords complex [PdCl{C6H3-2-(CH2PPh2)-6-(CH(CH3)PPh2)}] (7) in good yield. |
| Keywords: | PCP pincer ligands PCP pincer complexes Palladium complexes |
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