P NMR spectroscopy and discrete metallocycles from non-rigid ligands |
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Authors: | Magdalena Capó |
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Affiliation: | Departament de Química de la Universitat de les Illes Balears, 07071 Palma de Mallorca, Spain |
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Abstract: | The combination of the square-planar cis-protected Pt(II) with the 180° divergence bis(amidopyridine) bridging ligand, leads to quantitative self-assembled M2L2 macrocycles. The rhomboids are characterized, by multinuclear NMR and electrospray ionization mass spectroscopy. Size estimations for the rhomboid assemblies, using MM2 simulation, are given. |
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Keywords: | Macrocycles cis-Protected Pt(II) Non-rigid ligand Self-assembly 31P NMR |
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