Synthesis,characterization and X-ray crystal structure of the trigonal-planar copper(I) complex [Cu(MIBI)3] (MIBI = 2-methoxyisobutylisocyanide) |
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| Authors: | Micol Pasquali Valeria FerrettiAdriano Duatti |
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| Affiliation: | Laboratory of Nuclear Medicine, Department of Radiological Sciences, and Centre for Structural Diffractometry, Department of Chemistry, University of Ferrara, 44100 Ferrara, Italy |
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| Abstract: | The synthesis, spectroscopic and chromatographic characterization, and X-ray crystal structure of the complex tris(2-methoxyisobutylisocyano) copper(I) tetrafluoroborate, [Cu(MIBI)3][BF4], is reported. The Cu atom lies on threefold axis and is bonded to three 2-methoxyisobutylisocyano ligands in a perfect trigonal-planar coordination. The calculated and experimental powder-diffraction spectra of this complex are also reported. |
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| Keywords: | Trigonal-planar copper complexes Copper isocyanide complexes Cu-MIBI 99mTc-MIBI |
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