Systematisierung der Tieftemperaturmodifikationen homologer Thallium(I)-Salze aliphatischer Carbonsäuren durch ihre Mischbarkeitsbeziehungen |
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Authors: | J Lindau H -J König H -D Dörfler |
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Institution: | 1. Sektion Chemie, Martin-Luther-Universit?t Halle-Wittenberg, DDR
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Abstract: | By studying the miscibility in 12 binary systems of the thalliumsoaps TlC9 to TlC18, TlC20 and TlC22 the low-temperature modifications were classified. The members with shorter hydrocarbon chains up to TlC16 have the following phase sequence: phase II, phase I, neat-phase, isotropic liquid, whereas from TlC17 the sequence is: phase II, neatphase, isotropic liquid. Modifications of the same type are indicated by identical symbols. |
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