Reaction of trifluororacemic acid methyl ester with 1,3-dienes |
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| Authors: | A S Golubev M V Galakhov A F Kolomiets A V Fokin |
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| Institution: | (1) A. N. Nesmeyanov Institute of Heteroorganic Chemistry, Academy of Sciences of the USSR, Moscow |
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| Abstract: | The reaction of trifluororacemic acid with 1,3-dienes affords Diels-Alder reaction products in a high yield and with a high degree of specificity. Catalysis by SnCl4 changes the course of the reaction of the ester with isoprene, affording an ene reaction product.Translated from Izvestiya Akademii Nauk SSSR, Seriya Khimicheskaya, No. 1, pp. 141–145. January, 1991. |
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