Prototropic mechanism of intramolecular migration of the unpaired electron in the radical-cation of 3,6-di-tert-butylpyrocatechol orthocarbonate |
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| Authors: | N A Malysheva A I Prokof'ev T I Prokof'eva N N Bubnov S P Solodovnikov M I Kabachnik |
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| Institution: | (1) A. N. Nesmeyanov Institute of Heteroorganic Compounds, Academy of Sciences of the USSR, Moscow |
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| Abstract: | Conclusion The radical-cation of 3,6-di-tert-butylpyrocatechol orthocarbonate was obtained. It was established that the dynamic effects in its EPR spectra are due to the migration of a proton, attached by a hydrogen bond, from ligand to ligand.Translated from Izvestiya Akademii Nauk SSSR, Seriya Khimicheskaya, No. 5, pp. 1037–1039, May, 1988. |
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