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On the [2,3] sigmatropic rearrangement of allylic nitro compounds
Authors:Alameda-Angulo Celia  Quiclet-Sire Béatrice  Schmidt Elmar  Zard Samir Z
Institution:Laboratoire de Synthèse Organique Associé au CNRS, Ecole Polytechnique, 91128 Palaiseau Cedex, France.
Abstract:Allylic nitro compounds undergo relatively clean 2,3] sigmatropic rearrangement upon heating in refluxing 1,2-dichlorobenzene in the presence of DABCO to give the corresponding allylic alcohols via the intermediate allylic nitrite. reaction: see text]
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