| 两个三维柱层式单一手性配位化合物:合成、结构和性质（英文） |
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| 引用本文： | 徐中轩,柏雪累,蒙琴. 两个三维柱层式单一手性配位化合物:合成、结构和性质（英文）[J]. 无机化学学报, 2020, 36(1): 165-172 |
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| 作者姓名： | 徐中轩 柏雪累 蒙琴 |
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| 作者单位： | 遵义师范学院化学化工学院, 遵义 563002,遵义师范学院化学化工学院, 遵义 563002,遵义师范学院化学化工学院, 遵义 563002 |
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| 基金项目： | 国家自然科学基金（No.21761036）和贵州省科学技术基金（No.20181182）资助项目 |
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| 摘 要： | 在溶剂热合成条件下得到2个单一手性配位聚合物,即[Cd3((R)-CIA)2(bipy)2.5(H2O)2]·xGuest(1)和[Zn3((R)-CIA)(bmib)2(H2O)2 Cl]·H2O·xGuest(2)((R)-H3CIA=(R)-5-(1-羧基乙氧基)间苯二甲酸,bipy=4,4′-联吡啶,bmib=1,4-双(2-甲基-1H-咪唑-1-基)苯)。X射线单晶结构分析揭示配合物1和2都是柱层式结构的三维框架。从拓扑分析的角度看,配位物1具有(3,3,3,6,6)-连接的网络,拓扑符号为(4.5^2)2(4.8^2)2(42.6^8.8^3.10^2)(4^2.6^8.8^3.9^2)(5.8.9)2,而配合物2是(3,4,4)-连接的网络,拓扑符号为(6·7^2)2(6·7^5)2(6^2·7^4)。此外,对上述配合物的热稳定性、圆二色谱和荧光性质也做了研究。
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| 关 键 词： | 单一手性 乳酸衍生物 柱层式框架 拓扑 |
| 收稿时间： | 2019-06-05 |
| 修稿时间： | 2019-11-09 |
Two 3D Pillar-Layered Homochiral Coordination Complexes: Syntheses, Structures and Properties |
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| XU Zhong-Xuan,BAI Xue-Lei and MENG Qin. Two 3D Pillar-Layered Homochiral Coordination Complexes: Syntheses, Structures and Properties[J]. Chinese Journal of Inorganic Chemistry, 2020, 36(1): 165-172 |
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| Authors: | XU Zhong-Xuan BAI Xue-Lei MENG Qin |
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| Affiliation: | School of Chemistry and Chemical Engineering, Zunyi Normal College, Zunyi, Guizhou 563002, China,School of Chemistry and Chemical Engineering, Zunyi Normal College, Zunyi, Guizhou 563002, China and School of Chemistry and Chemical Engineering, Zunyi Normal College, Zunyi, Guizhou 563002, China |
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| Abstract: | Two homochiral coordination polymers[Cd3((R)-CIA)2(bipy)2.5(H2O)2]·xGuest (1) and[Zn3((R)-CIA)(bmib)2(H2O)2Cl]·H2O·xGuest (2) ((R)-H3CIA=(R)-5-(1-carboxyethoxy) isophthalic acid, bipy=4,4''-bipyridine, bmib=1,4-bis(2-methyl-1H-imidazol-1-yl)benzene) were obtained under solvothermal reaction conditions. X-ray single crystal structure analysis reveals that complexes 1 and 2 are all 3D pillar-layered frameworks. From the viewpoint of structural topology, complex 1 possesses a (3,3,3,6,6)-connected net with a point symbol of (4.52)2(4.82)2(42.68.83. 102)(42.68.83.92)(5.8.9)2, while complex 2 is a (3,4,4)-connected net with a point symbol of (6·72)2(6·75)2(62·74). Moreover, thermal stabilities, CD spectra and luminescent properties of these new complexes have been studied. |
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| Keywords: | homochiral lactic acid derivative pillar-layered framework topology |
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