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Macrocycle-based oligo- and polylactides: synthesis and prospects of application
Authors:Stoikov  I I  Padnya  P L  Mostovaya  O A  Vavilova  A A  Gorbachuk  V V  Shurpik  D N  Evtugin  G A
Institution:1.A. M. Butlerov Chemical Institute, Kazan Federal University, 18 ul. Kremlevskaya, 420008, Kazan, Russian Federation
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Abstract:

The review considers methods for modifying oligo- and polymers of lactic acid by macrocyclic moieties (cyclodextrin, tetrapyrrole, and calixarene) and the effect of modifiers on the complexing, thermal, and aggregation properties. Analytical characteristics of oligolactide-based sensors and biosensors are discussed, with particular emphasis on the mechanism of signal generation and the contribution of modified materials to the selectivity and sensitivity of analysis.

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