| 基于3，4'，5-联苯三羧酸构筑的钕配合物的合成、结构、荧光、光催化及磁性质 |
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| 引用本文： | 郑欢,焦媛,冯思思.基于3，4'，5-联苯三羧酸构筑的钕配合物的合成、结构、荧光、光催化及磁性质[J].无机化学学报,2021,37(9):1691-1699. |
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| 作者姓名： | 郑欢 焦媛 冯思思 |
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| 作者单位： | 山西大学分子科学研究所, 化学生物学与分子工程教育部重点实验室, 太原 030006 |
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| 基金项目： | 国家自然科学基金（No.21671124）、山西省1331工程重点创新研究团队和山西省自然科学基金（No.201701D121039）资助。 |
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| 摘 要： | 采用NdCl3·6H2O和3，4''，5-联苯三羧酸（H3bpt）为原料在DMF/H2O混合溶剂热条件下合成得到一个三维钕配合物{Nd （bpt）（DMF）（H2O）]·2H2O}n（1），并通过红外光谱、元素分析、单晶及粉末X射线衍射表征了配合物1的结构。单晶衍射结果表明，配合物1具有（5，5）-连接的三维结构，拓扑符号为（44·63·83）（48 62）。此外，对配合物1的热稳定性、荧光性质、光催化降解染料及磁性质进行了详细研究。
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| 关 键 词： | 钕金属有机框架 3，4''，5-联苯三羧酸 晶体结构 荧光 光催化 磁性质 |
| 收稿时间： | 2021/2/19 0:00:00 |
| 修稿时间： | 2021/7/15 0:00:00 |
Synthesis, Structure, Luminescence, Photocatalytic and Magnetic Properties of a Neodymium Complex Constructed from Biphenyl-3,4',5-tricarboxylic Acid |
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| ZHENG Huan,JIAO Yuan,FENG Si-Si.Synthesis, Structure, Luminescence, Photocatalytic and Magnetic Properties of a Neodymium Complex Constructed from Biphenyl-3,4',5-tricarboxylic Acid[J].Chinese Journal of Inorganic Chemistry,2021,37(9):1691-1699. |
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| Authors: | ZHENG Huan JIAO Yuan FENG Si-Si |
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| Institution: | Institute of Molecular Science, Key Laboratory of Chemical Biology and Molecular Engineering of Ministry of Education, Shanxi University, Taiyuan 030006, China |
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| Abstract: | A Nd3+ MOF, namely {Nd(bpt)(DMF)(H2O)]·2H2O}n (1) (H3bpt=biphenyl-3,4'',5-tricarboxylic acid, DMF=N,N-dimethylformamide), has been obtained by the self-assemble reaction of NdCl3·6H2O and H3bpt ligand under solvothermal conditions (DMF/H2O). Complex 1 was characterized by means of elemental analysis, infrared spectroscopy, powder X-ray diffraction and single-crystal X-ray diffraction analyses. Single-crystal X-ray structural analysis reveals that complex 1 displays three-dimensional frameworks featuring a (5,5)-connected topological network with the point symbol of 44·63·83)(48 62). In addition, the thermal stability, luminescent properties, photocatalytic behaviour, and magnetic property of complex 1 were also investigated in detail in the solid state. |
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| Keywords: | Nd3+ metal-organic framework biphenyl-3 4'' 5-tricarboxylic acid crystal structure luminescence photocatalysis magnetism |
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