| 胍基锆酰胺配合物与四氯化碳的反应生成氯化锆胍基衍生物 |
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| 引用本文： | Bhavna Sharm,薛子陵.胍基锆酰胺配合物与四氯化碳的反应生成氯化锆胍基衍生物[J].无机化学学报,2020,36(6):1157-1162. |
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| 作者姓名： | Bhavna Sharm 薛子陵 |
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| 作者单位： | 田纳西大学化学系, 诺克斯维尔市 37996, 美国 |
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| 基金项目： | 美国国家科学基金（No.CHE-1362548，CHE-1900296）资助。 |
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| 摘 要： | 四氯化碳与Zr（NMe2）2iPrNC（NMe2）NiPr]2（1）反应先生成中间体ZrCl（NMe2）2iPrNC（NMe2）NiPr]2（2），然后生成ZrCl2iPrNC（NMe2）NiPr]2（3）。该反应可能是自由基反应。另外，配合物2可由ZrCl（NMe2）3与二异丙基碳二亚胺iPr-N=C=N-iPr反应制备。对配合物2进行了核磁共振（NMR）和元素分析。
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| 关 键 词： | 锆 氯 酰胺配合物 |
| 收稿时间： | 2020/2/28 0:00:00 |
| 修稿时间： | 2020/4/5 0:00:00 |
Formation of Zirconium Chloride Guanidinate Complexes from the Reaction of their Amide Analog with CCl4 |
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| Bhavna Sharm,XUE Zi-Ling.Formation of Zirconium Chloride Guanidinate Complexes from the Reaction of their Amide Analog with CCl4[J].Chinese Journal of Inorganic Chemistry,2020,36(6):1157-1162. |
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| Authors: | Bhavna Sharm XUE Zi-Ling |
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| Institution: | Department of Chemistry, the University of Tennessee, Knoxville, Tennessee 37996, USA |
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| Abstract: | Reaction of CCl4 with zirconium amide guanidinate Zr(NMe2)2 iPrNC(NMe2)NiPr]2 (1) has been found to give ZrCl(NMe2) iPrNC(NMe2)NiPr]2 (2) as an intermediate and later ZrCl2 iPrNC(NMe2)NiPr]2 (3). The reaction is likely radical in nature. Complex 2 has been independently prepared from the reaction of ZrCl(NMe2)3 with diisopropylcarbodiimide, iPr-N=C=N-iPr, and characterized by nuclear magnetic resonance (NMR) and elemental analysis. |
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| Keywords: | zirconium chlorine amide complex |
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