| 基于芳香四羧酸构筑的两种配位聚合物的荧光及磁性质（英文） |
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| 引用本文： | 翟丽军,张婕,高玲玲,高婷,贾焦焦,牛宇岚,胡拖平. 基于芳香四羧酸构筑的两种配位聚合物的荧光及磁性质（英文）[J]. 无机化学学报, 2020, 36(1): 173-182 |
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| 作者姓名： | 翟丽军 张婕 高玲玲 高婷 贾焦焦 牛宇岚 胡拖平 |
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| 作者单位： | 中北大学理学院化学系, 太原 030051;太原工业学院化学与化工系, 太原 030008,中北大学理学院化学系, 太原 030051,中北大学理学院化学系, 太原 030051,中北大学理学院化学系, 太原 030051,中北大学理学院化学系, 太原 030051;太原工业学院化学与化工系, 太原 030008,1 中北大学理学院化学系, 太原 030051;太原工业学院化学与化工系, 太原 030008,中北大学理学院化学系, 太原 030051 |
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| 基金项目： | 山西省国际科技合作项目（No.201803D421080）资助 |
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| 摘 要： | 在溶剂热条件下,基于芳香四羧酸合成了2种新颖的配位聚合物:{[Zn2(tptc)(1,4-bimb)2]·H2O}n(1)和{[Ni(tptc)0.5(1,2-bimb)(H2O)]·H2O}n(2),其中,tptc为对-三联苯-3,3″,5,5″-四羧酸,1,4-bimb为1,4-二(咪唑-1-亚甲基)苯,1,2-bimb为1,2-二(咪唑-1-亚甲基)苯。结构分析表明,1为三维结构,拓扑符号为(86);2为二维层状网络,通过氢键相互作用进一步扩展为三维超分子结构。此外,我们还研究了1对阳离子、阴离子的荧光感应以及2的磁性质。
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| 关 键 词： | 芳香四羧酸 配位聚合物 荧光性质 磁性质 |
| 收稿时间： | 2019-06-26 |
| 修稿时间： | 2019-10-01 |
Two Coordination Polymers Constructed by Aromatic Tetracarboxylic Acid: Luminescent and Magnetic Properties |
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| ZHAI Li-Jun,ZHANG Jie,GAO Ling-Ling,GAO Ting,JIA Jiao-Jiao,NIU Yu-Lan and HU Tuo-Ping. Two Coordination Polymers Constructed by Aromatic Tetracarboxylic Acid: Luminescent and Magnetic Properties[J]. Chinese Journal of Inorganic Chemistry, 2020, 36(1): 173-182 |
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| Authors: | ZHAI Li-Jun ZHANG Jie GAO Ling-Ling GAO Ting JIA Jiao-Jiao NIU Yu-Lan HU Tuo-Ping |
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| Affiliation: | Department of Chemistry, College of Science, North University of China, Taiyuan 030051, China;Department of Chemistry and Chemical Engineering, Taiyuan Institute of Technology, Taiyuan 030008, China,Department of Chemistry, College of Science, North University of China, Taiyuan 030051, China,Department of Chemistry, College of Science, North University of China, Taiyuan 030051, China,Department of Chemistry, College of Science, North University of China, Taiyuan 030051, China,Department of Chemistry, College of Science, North University of China, Taiyuan 030051, China;Department of Chemistry and Chemical Engineering, Taiyuan Institute of Technology, Taiyuan 030008, China,1 Department of Chemistry, College of Science, North University of China, Taiyuan 030051, China;Department of Chemistry and Chemical Engineering, Taiyuan Institute of Technology, Taiyuan 030008, China and Department of Chemistry, College of Science, North University of China, Taiyuan 030051, China |
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| Abstract: | Two new coordination polymers (CPs) based on H4tptc, namely, {[Zn2(tptc)(1,4-bimb)2]·H2O}n (1) and {[Ni(tptc)0.5(1,2-bimb)(H2O)]·H2O}n (2) (H4tptc=p-terphenyl-3,3",5,5"-tetracarboxylic acid, 1,4-bimb=1,4-bis (imid-azol-1-ylmethyl) benzene, 1,2-bimb=1,2-bis (imidazol-1-ylmethyl) benzene), have been synthesized under solvo-thermal conditions. The structural analyses reveal that complex 1 shows a 3D structure with the symbol of (86), while complex 2 presents a 2D layer network, which is further expanded into a 3D supramolecular structure through H-bonding interactions. Furthermore, the luminescence sensing of 1 for cations, anions as well as magnetic property of 2 have also been studied. |
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| Keywords: | aromatic tetracarboxylic acid coordination polymers luminescent properties magnetic properties |
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