Synthesis,growth, and characterization of a new NLO material 3-(2,3-dimethoxyphenyl)-1-(pyridin-2-yl)prop-2-en-1-one |
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| Authors: | B. Ganapayya A. Jayarama Ravish Sankolli Venkatesha R. Hathwar S.M. Dharmaprakash |
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| Affiliation: | 1. Department of Physics, SDM College, Ujire 574 240, India;2. Department of Physics, Mangalore Institute of Technology & Engineering, Moodabidri 574 225, India;3. Solid State and Structural Chemistry Unit, Indian Institute of Science, Bangalore 560 012, India;4. Department of Studies in Physics, Mangalore University, Mangalagangotri, Mangalore 574 199, India |
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| Abstract: | 3-(2,3-Dimethoxyphenyl)-1-(pyridin-2-yl)prop-2-en-1-one (DMPP) a potential second harmonic generating (SHG) has been synthesized and grown as a single crystal by the slow evaporation technique at ambient temperature. The structure determination of the grown crystal was done by single crystal X-ray diffraction study. DMPP crystallizes with orthorhombic system with cell parameters a = 20.3106(8) Å, b = 4.9574(2) Å, c = 13.4863(5) Å, α = 90°, β = 90°, γ = 90° and space group Pca21. The crystals were characterized by FT-IR, thermal analysis, UV–vis–NIR spectroscopy and SHG measurements. Various functional groups present in DMPP were ascertained by FTIR analysis. DMPP is thermally stable up to 80 °C and optically transparent in the visible region. The crystal exhibits SHG efficiency comparable to that of KDP. |
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