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Synthesis of 4-(2-chloroethoxy)phenyl glycosides and their modification |
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| Authors: | Kondakov N. N. Panova M. V. Abronina P. I. Zinin A. I. Shpirt A. M. Kononov L. O. |
| Affiliation: | 1.N. D. Zelinsky Institute of Organic Chemistry, Russian Academy of Sciences, 47 Leninsky prosp., 119991, Moscow, Russian Federation ; |
| Abstract: | 4-(2-Chloroethoxy)phenyl (CEP) aglycon belongs to the class of Janus aglycons and has already been used as a pre-spacer in the synthesis of neoglycoconjugates and as a temporary protective group in the synthesis of oligosaccharides. In the present work, a set of glycosides of various monosaccharides containing CEP aglycon was synthesized. The possibility of modification of CEP aglycon was demonstrated using the corresponding lactoside as an example. |
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