| 四个CyB5Q[5]-Ca配合物的晶体结构和在不同阴离子环境下的不同配位状态 |
| |
| 引用本文： | 邓德朋,陈明华,刘元东,钱丙飞,夏位敏,易君明.四个CyB5Q[5]-Ca配合物的晶体结构和在不同阴离子环境下的不同配位状态[J].无机化学学报,2022,38(10):1927-1938. |
| |
| 作者姓名： | 邓德朋 陈明华 刘元东 钱丙飞 夏位敏 易君明 |
| |
| 作者单位： | 兴义民族师范学院生物与化学学院, 兴义 562400 |
| |
| 基金项目： | 贵州省黔西南州科技局科技计划项目（No.[2021]2021-1-09）、兴义民族师范学院教授基金项目（No.[2019]19XYJS02）、大学生创新创业项目（No.[2021]202110666023，[2021]S202110666080）资助 |
| |
| 摘 要： | 在不同阴离子介质中，利用瓜环家族新成员CyB5Q5]与钙离子生成了4个CyB5Q5]-Ca配合物（1~4），用X射线单晶衍射确定了它们的结构。晶体结构表明，在Cl-、ZnCl4]2-、ZnCl4]2-+ClO4-和ClO4-环境下，分别生成了不同配位类型的配合物。
|
| 关 键 词： | 环丁烷取代瓜环 瓜环-金属配合物 超分子有机骨架 |
| 收稿时间： | 2021/12/9 0:00:00 |
| 修稿时间： | 2022/7/10 0:00:00 |
Crystal Structure of Four CyB5Q[5]-Ca Complexes: The Different Coordination States in Different Anionic Environments |
| |
| DENG De-Peng,CHEN Ming-Hu,LIU Yuan-Dong,QIAN Bing-Fei,XIA Wei-Min,YI Jun-Ming.Crystal Structure of Four CyB5Q[5]-Ca Complexes: The Different Coordination States in Different Anionic Environments[J].Chinese Journal of Inorganic Chemistry,2022,38(10):1927-1938. |
| |
| Authors: | DENG De-Peng CHEN Ming-Hu LIU Yuan-Dong QIAN Bing-Fei XIA Wei-Min YI Jun-Ming |
| |
| Institution: | School of Biology and Chemistry, Minzu Normal University of Xingyi, Xingyi, Guizhou 562400, China |
| |
| Abstract: | Four CyB5Q5]-Ca complexes (1-4) have been synthesized by the new member of the cucurbituril family (CyB5Q5]) and calcium ions in different anionic media. Their structures have been characterized by X-ray single-crystal diffraction. Their crystal structures show that complexes of different coordination types are generated in different environments of Cl-,ZnCl4]2-,ZnCl4]2-+ClO4-, and ClO4-, respectively. The coordination number of complexes 1, 2, 3, and 4 are 6, 8, 7, and 6, respectively. |
| |
| Keywords: | cyclobutanocurbit[n]uril cucurbituril-metal complex supramolecular organic frameworks |
|
| 点击此处可从《无机化学学报》浏览原始摘要信息 |
| 点击此处可从《无机化学学报》下载免费的PDF全文 |
|
