Protodesilylation of 2,6-disubstituted silyphosphinines. Experimental and theoretical study |
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Authors: | Blug Matthias Piechaczyk Olivier Fustier Marie Mézailles Nicolas Le Floch Pascal |
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Affiliation: | Laboratoire Hétéroéléments et Coordination, Ecole Polytechnique, CNRS, Palaiseau, France. |
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Abstract: | 2,6-Disilylphosphinines react with HCl in ethereal solution to cleanly yield the corresponding 2,6-unsubstituted derivatives. DFT calculations allowed rationalization of the mechanism of this protodesilylation. |
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