Aluminum-controlled reactivity and diastereoselectivity toward radical reactions of optically active aldimines with metallic samarium |
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| Authors: | Yanada R Okaniwa M Kaieda A Ibuka T Takemoto Y |
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| Institution: | Graduate School of Pharmaceutical Sciences, Kyoto University, Yoshida, Sakyo-ku, Kyoto 606-8501, Japan. ryanada@pharm.kyoto-u.ac.jp |
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| Abstract: | The intermolecular pinacol-type coupling reaction and allylation reaction of optically active imines bearing a beta-hydroxy group were performed stereoselectively with metallic samarium after treatment of the imines with trimethylaluminum. |
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