The pentanuclear Fe(II) cluster [(C5H4)6Fe5]2-: bringing together ferrocene sandwiches and homoleptic Fe(II)-cyclopentadienyl sigma-complexes |
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| Authors: | Sänger Ingeborg Heilmann Julia B Bolte Michael Lerner Hans-Wolfram Wagner Matthias |
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| Affiliation: | Institut für Anorganische Chemie, J. W. Goethe-Universit?t Frankfurt, Marie-Curie-Strasse 11, D-60439 Frankfurt (Main), Germany. |
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| Abstract: | Reaction of [(fc)3(Li)6.(TMEDA)2] with FeCl2 gives the pentanuclear iron complex [(fc)3(Fe)2(Li)2.(TMEDA)2] featuring two ferra[1]ferrocenophane moieties bridged by a 1,1'-ferrocenediyl unit; the non-ferrocene Fe(II) ions are tetra-coordinate and adopt a high-spin state. |
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