| STUDIES ON POLYMERIZATION KINETICS OF METHYL METHACRYLATE AT HIGH CONVERSION |
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| 作者姓名： | 李伯耿 于在璋 蔡启振 李宝芳 |
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| 作者单位： | Department of Chemical Engineering，Zhejiang University，Hangzhou，Department of Chemical Engineering，Zhejiang University，Hangzhou，Department of Chemical Engineering，Zhejiang University，Hangzhou，Department of Chemical Engineering，Zhejiang University，Hangzhou |
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| 摘 要： | The bulk polymerization of methyl methacrylate which was carried out in a metallic dilatometer and in a differential scanning calorimeter has been studied over the complete course of the reaction. An attempt was made to quantitatively express the relation on the onset of gel effect and the final conversion with polymerization conditions such as temperature, kinds and concentration of initiators. It was demonstrated further that the final conversion of polymerization in homogeneous ideal systems is only dependent upon the reaction temperature.
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| 收稿时间： | 1983-08-19 |
STUDIES ON POLYMERIZATION KINETICS OF METHYL METHACRYLATE AT HIGH CONVERSION* |
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| LI Bogeng,YU Zaizhang,CAI Qizen,LI Baofang.STUDIES ON POLYMERIZATION KINETICS OF METHYL METHACRYLATE AT HIGH CONVERSION[J].Chinese Journal of Polymer Science,1984,0(1):82-91. |
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| Authors: | LI Bogeng YU Zaizhang CAI Qizen LI Baofang |
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| Institution: | Department of Chemical Engineering; Zhejiang University; Hangzhou |
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| Abstract: | The bulk polymerization of methyl methacrylate which was carried out in a metallic dilatometer and in a differential scanning calorimeter has been studied over the complete course of the reaction. An attempt was made to quantitatively express the relation on the onset of gel effect and the final conversion with polymerization conditions such as temperature, kinds and concentration of initiators. It was demonstrated further that the final conversion of polymerization in homogeneous ideal systems is only dependent upon the reaction temperature. |
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