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A definition of metastability for Markov processes with detailed balance
Authors:F Leyvraz  H Larralde  D P Sanders
Institution:(1) Centro de Ciencias Físicas, UNAM; Apartado postal 48-3, CP, 62251 Cuernavaca Morelos, Mexico
Abstract:A definition of metastable states applicable to arbitrary finite state Markov processes satisfying detailed balance is discussed. In particular, we identify a crucial condition that distinguishes genuine metastable states from other types of slowly decaying modes and which leads to properties similar to those postulated in the restricted ensemble approach 1]. The intuitive physical meaning of this condition is simply that the total equilibrium probability of finding the system in the metastable state is negligible. As a concrete application of our formalism we present preliminary results on a 2D kinetic Ising model.
Keywords:02  50  Ga Markov processes  05  20  Gg Classical ensemble theory  05  70  Ln Nonequilibrium and irreversible thermodynamics
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