| A STUDY OF THE POLYMERIZATION MECHANISM OF ACETONITRILE IN GLOW DISCHARGE |
| |
| 引用本文： | 余青松,叶牧,卢丽珍,陈捷,王佛松,长田义仁. A STUDY OF THE POLYMERIZATION MECHANISM OF ACETONITRILE IN GLOW DISCHARGE[J]. 高分子科学, 1988, 0(2): 172-177 |
| |
| 作者姓名： | 余青松 叶牧 卢丽珍 陈捷 王佛松 长田义仁 |
| |
| 作者单位： | Changchun Institute of Applied Chemistry，Academia Sinica，Changchun Institute of Applied Chemistry，Academia Sinica，Changchun Institute of Applied Chemistry，Academia Sinica，Changchun Institute of Applied Chemistry，Academia Sinica，Changchun Institute of Applied Chemistry，Academia Sinica，Department of Chemistry，College of Liberal Arts Science，Ibaraki University，Japan |
| |
| 摘 要： | Plasma polymerization of acetonitrile was carried out by a capacitively coupled RF plasma apparatus with external electrodes under some different reaction conditions such as discharge power. By investigating the informations provided by the polymer deposition regularities, IR spectra and elementary analysis results, the polymerization mechanism of acetonitrile in glow discharge have been investigated. The results show that acetonitrile polymerized in glow discharge mainly through hydrogen detachment for initiation at lower energy levels and the role that opening C≡N triple bond played in polymerization became more important at higher energy levels.
|
| 收稿时间： | 1987-04-07 |
A STUDY OF THE POLYMERIZATION MECHANISM OF ACETONITRILE IN GLOW DISCHARGE |
| |
| YU Qingsong,YE Mu,LU Lizhen,CHEN Jie,WANG Fosong,Yoshihito Osada. A STUDY OF THE POLYMERIZATION MECHANISM OF ACETONITRILE IN GLOW DISCHARGE[J]. Chinese Journal of Polymer Science, 1988, 0(2): 172-177 |
| |
| Authors: | YU Qingsong YE Mu LU Lizhen CHEN Jie WANG Fosong Yoshihito Osada |
| |
| Affiliation: | Changchun Institute of Applied Chemistry; Academia Sinica; Department of Chemistry; College of Liberal Arts Science; Ibaraki University; Japan |
| |
| Abstract: | Plasma polymerization of acetonitrile was carried out by a capacitively coupled RF plasma apparatus with external electrodes under some different reaction conditions such as discharge power. By investigating the informations provided by the polymer deposition regularities, IR spectra and elementary analysis results, the polymerization mechanism of acetonitrile in glow discharge have been investigated. The results show that acetonitrile polymerized in glow discharge mainly through hydrogen detachment for initiation at lower energy levels and the role that opening C=N triple bond played in polymerization became more important at higher energy levels. |
| |
| Keywords: | Plasma polymerization Acetonitrile Glow discharge Mechanism |
| 本文献已被 CNKI 等数据库收录！ |
| 点击此处可从《高分子科学》浏览原始摘要信息 |
|
点击此处可从《高分子科学》下载全文 |
